一步法合成5-甲基海因

以氰化钠、碳酸铵、乙醛等为原料，常压下一步反应得到５甲基海因，总收率７０２％。其最佳操作条件为：反应温度７５℃，反应时间３ｈ，原料碳酸铵与氰化钠之比为２∶１，酸化回流ｐＨ值为２，酸化回流时间２ｈ。     

聚氨酯改性聚异氰脲酸酯弹性体的合成和热性能分析

本文介绍用２，４，６－三（二甲胺基甲基）苯酚（ＤＭＰ－３０）作催化剂，采用一步法工艺制备聚氨酯改性聚异氰脲酸酯弹性体的研究工作，并用红外光谱、差热分析、热失重等方法对所制弹性体进行了定性、定量热性能分析。结果表明，通过调节催化剂用量、两组分摩尔比等工艺条件，可以使整个反应过程在１分钟之内完成，适合ＲＩＭ加工工艺；由红外光谱法和差热分析可定性确知所制材料中含有聚异氰脲酸酯三聚体和氨酯，由热失重分析可     

Fast economic model predictive control based on NLP-sensitivities

This study adapts the advanced step NMPC framework to Economic NMPC. Here, sufficient conditions for nominal stability are derived for NMPC controllers that incorporate economic stage costs with appropriate regularization. To guarantee these conditions, we derive a constructive strategy to calculate the regularization term directly. Moreover, we extend the sensitivity components in the advanced step NMPC framework to consider a rigorous path-following algorithm. This approach accounts for active set changes and allows much weaker constraint qualifications. Moreover, using an ℓ₁ formulation of the NMPC problem satisfies these constraint qualifications and allows more reliable solution of the moving horizon optimization problem, even in the presence of noise. Finally, all of these concepts are demonstrated on a detailed case study with a continuously stirred tank reactor.     

主流视频编解码软件的硬件性能分析与设计

网络视频会议以及高清视频点播等应用的广泛流行,对视频编解码的编码质量以及编码速度提出了更高的要求。为帮助硬件设计人员设计更强大的专用处理器去适应视频编解码应用的发展趋势,并评估处理器设计的合理性和正确性,对视频编解码进行分析和测试,提出一套基准测试程序。采用自顶向下的分析方法,以流行性、编解码效率、压缩质量和开源性为标准,选取主流的视频编解码软件,进行热点函数分析。抽取变换、量化以及滤波过程中的热点函数,使之成为视频编解码测试程序,为其构造典型输入集。通过分析真实硬件平台上这些测试程序的计算和访存特性,给出处理器设计的建议。结果证明,该基准测试程序使用10%的代码量即可反映视频编解码过程的主要特征,对处理器设计具有指导意义。     

LDPC码改进的量化自适应偏移最小和算法

为减小低密度奇偶校验（LDPC）码的量化译码算法的实现复杂度,提出了一种改进的4比特量化自适应偏移最小和（AOMS）译码算法。改进的AOMS译码算法中引入了预设的固定迭代次数作为启动偏移量修正因子自适应选择的条件;设计了一种4比特非均匀数据量化方案,保证量化数据的取值范围既能较好地满足外信息的动态范围,又能简单实现优化的量化偏移量修正因子。仿真结果表明,与浮点译码算法相比较,改进的量化AOMS译码算法的译码性能损失较小。     

一种新变步长LMS算法及在自适应波束形成中的应用

LMS算法是智能天线自适应波束形成算法中的经典算法,由于其步长固定,造成收敛速度和稳态失调之间的矛盾。为了解决这一问题,提出一种新的变步长LMS算法,并在算法中引入误差信号的自相关估计,大大降低了噪声的干扰,对算法进行仿真,得到了最优的参数设置。利用蒙特卡罗方法对算法进行了性能评估,与传统的LMS算法、NLMS算法相比,新的变步长LMS算法具有更快的收敛速度和较小的稳态误差及优良的抗噪性能。     

基于固定电压法结合P＆O法MPPT控制策略研究

对光伏发电控制系统提出了一种新型的最大功率点跟踪（MPPT）控制方法。即在外界环境或负载突变时,先采用固定电压法将光伏阵列的工作点调整到最大功率点附近,以保证跟踪的快速性;并且引入新型的扰动观察法,对最大功率点的稳态特性进行优化,可有效减小光伏阵列的输出功率在最大功率点的振荡现象。通过仿真验证了上述方法的有效性。     

Ammonia synthesis: The bellwether reaction in heterogeneous catalysis

This is a personal account of the Havreholm Conference with a choice of topics dealing with catalytic ammonia synthesis. Among the general concepts that were retained are: the rate determining step with rates of adsorption and desorption of nitrogen; the direct activated dissociative adsorption of N₂; the surface crystalline anisotropy of iron; the role of promoters in industrial iron based catalysts; and the atomic structure of the metallic surface on the industrial multiply promoted catalyst. Finally, a new isotope jump technique to measure an upper limit to the real turnover frequency is discussed.     

六偏磷酸钠的生产工艺

本文对六偏磷酸钠的性质、用途及生产工艺进行论述并介绍从日本引进１．５ｋｔ／ａ食品级六偏磷酸钠生产装置投产运行情况。     

Bayesian estimation of Dirichlet mixture model with variational inference

In statistical modeling, parameter estimation is an essential and challengeable task. Estimation of the parameters in the Dirichlet mixture model (DMM) is analytically intractable, due to the integral expressions of the gamma function and its corresponding derivatives. We introduce a Bayesian estimation strategy to estimate the posterior distribution of the parameters in DMM. By assuming the gamma distribution as the prior to each parameter, we approximate both the prior and the posterior distribution of the parameters with a product of several mutually independent gamma distributions. The extended factorized approximation method is applied to introduce a single lower-bound to the variational objective function and an analytically tractable estimation solution is derived. Moreover, there is only one function that is maximized during iterations and, therefore, the convergence of the proposed algorithm is theoretically guaranteed. With synthesized data, the proposed method shows the advantages over the EM-based method and the previously proposed Bayesian estimation method. With two important multimedia signal processing applications, the good performance of the proposed Bayesian estimation method is demonstrated.